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Acid emulsifier for increasing production of acid fracturing: a "tool for increasing efficiency" in oil and gas field development

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Acid emulsifier for increasing production of acid fracturing: a "tool for increasing efficiency" in oil and gas field development
  • March 21, 2025

Acid emulsifier for increasing production of acid fracturing: a "tool for increasing efficiency" in oil and gas field development

1. What is acid emulsifier for increasing production of acid fracturing?

In the process of oil and gas field development, acid fracturing technology is often used to increase the production of oil and gas wells. This technology injects acid into the oil layer or gas layer, and uses the chemical dissolution of the acid to dissolve the carbonate minerals in the rock, thereby forming cracks, increasing the flow channel of oil and gas, and improving the recovery rate of oil and gas. However, the distribution and effect of the acid in the formation are often affected by many factors, such as the fluidity of the acid and the contact area with the formation. In order to overcome these problems, acid emulsifier for increasing production of acid fracturing came into being. It is a special chemical additive that can form a stable emulsion between the acid and the oil phase or the water phase, thereby improving the fluidity of the acid, ensuring the uniform distribution of the acid in the formation, improving the effect of acid fracturing, and thus increasing the production of oil and gas. It can be said that the acid emulsifier for increasing production and fracturing is an indispensable and important tool in the development of oil and gas fields, providing a strong guarantee for the efficient exploitation of oil and gas wells.

2. Characteristics of acid emulsifier for increasing production and fracturing

The acid emulsifier for increasing production and fracturing has many significant characteristics, which enable it to play a unique role in the development of oil and gas fields. First, it has excellent emulsification stability, which can significantly reduce the oil-water interfacial tension and form a stable emulsion between the oil phase and the water phase. This stability is crucial to the acid fracturing process because it can ensure the uniform distribution of the acid in the formation and prevent the acid from being stratified or aggregated prematurely in the formation, thereby improving the acidizing effect and enabling the acid to contact and react with the carbonate minerals in the rock more effectively, thereby forming more cracks and improving the fluidity of oil and gas. Secondly, the emulsifier can also significantly reduce the flow resistance of the emulsified acid in the pipeline, which is of great significance for improving construction efficiency, reducing equipment wear and reducing energy consumption. By reducing the flow resistance, the acid can be injected into the formation more smoothly, improving the speed and efficiency of construction, while reducing the wear on the equipment, extending the service life of the equipment and reducing the construction cost. In addition, the emulsifier also has good high temperature resistance, which is particularly important for oil and gas field development because the formation temperature is often high. Even in a high temperature environment, the emulsifier can still maintain its emulsification stability, ensuring the uniform distribution and effective action of the acid, thereby ensuring that the effect of acid fracturing is not affected by the high temperature environment. At the same time, with the continuous improvement of environmental protection requirements, the environmental friendliness of acid fracturing acid emulsifiers has also received increasing attention. Some new emulsifiers use biodegradable ingredients in their formula design, reducing the potential impact on the environment and meeting the requirements of sustainable development. In addition, the emulsifier also has good compatibility with the rocks and fluids in the formation, and will not react adversely with the minerals or fluids in the formation, thereby avoiding damage or blockage to the formation and ensuring the long-term stable production of oil and gas wells.

3. Classification of acid emulsifiers for increasing production and acid fracturing

According to their chemical composition and structure, acid emulsifiers for increasing production and acid fracturing can be divided into many types, among which Coco dimethyl quat and Tallow dimethylammonium chloride are two common emulsifiers.

Coco dimethyl quat

Its molecular formula is (C11H23−C15H31)2N(CH3)2Cl. This emulsifier is a cationic surfactant with two long-chain alkyl groups in its molecular structure, usually derived from coconut oil. This structure gives it good emulsification and surface activity, and it can remain stable over a wide temperature and pH range. Di-coconut oil quaternary ammonium salt is widely used in water-in-oil emulsified acid systems, which can effectively reduce the surface tension of the acid and improve the permeability and uniformity of the acid in the formation. In addition, it also has good antistatic and antibacterial properties, which helps to improve the safety of the acid fracturing process. In practical applications, di-coconut oil quaternary ammonium salt can significantly improve the effect of acid fracturing and significantly increase the production of oil and gas wells.

Tallow dimethylammonium chloride

Its molecular formula is (C17H35)2N(CH3)2Cl. It is also a cationic surfactant with two long-chain alkyl groups in its molecular structure, usually derived from tallow. This emulsifier has a high melting point and good thermal stability, and can remain stable under high temperature conditions. Tallow dimethylammonium salt is mainly used in oil-in-water emulsified acid systems, which can effectively reduce the oil-water interfacial tension and form a stable oil-in-water emulsion, thereby improving the permeability and uniformity of the acid in the formation. This emulsifier is particularly suitable for acid fracturing operations in high-temperature and high-salt formations, and can maintain good performance under complex formation conditions. In addition, Tallow dimethylammonium salt also has good biodegradability, has little impact on the environment, and meets environmental protection requirements.

4. Application of acid emulsifier for increasing production acid fracturing

Acid emulsifier for increasing production acid fracturing has a wide range of applications in oil and gas field development, and its importance is self-evident. By using this emulsifier, the effect of acid fracturing can be significantly improved. Emulsifiers can stabilize emulsified acid and ensure the uniform distribution of acid in the formation, so as to dissolve carbonate minerals more effectively, form more cracks, and improve the fluidity of oil and gas. This can not only increase the production of oil and gas wells, but also extend the production life of oil and gas wells, providing strong support for the efficient development of oil and gas fields. In addition, emulsifiers can also reduce the flow resistance of emulsified acid in pipelines, improve construction efficiency, reduce equipment wear and energy consumption. This not only reduces construction costs, but also improves the safety and reliability of construction. With the continuous deepening of oil and gas field development, the formation conditions are becoming more and more complex, and the requirements for acid fracturing technology are becoming higher and higher. The high temperature resistance of the acid fracturing acid emulsifier enables it to adapt to the acid fracturing operation of high-temperature oil and gas fields, ensuring that it can still maintain a good emulsification effect under high temperature environment. At the same time, with the continuous improvement of environmental protection requirements, some new emulsifiers use biodegradable ingredients in the formulation design, which reduces the potential impact on the environment and meets the requirements of sustainable development. In addition, the emulsifier also has good compatibility with the rocks and fluids in the formation, will not cause damage or blockage to the formation, and ensure the long-term stable production of oil and gas wells. In short, acid fracturing acid emulsifiers play an important role in increasing oil and gas production, reducing construction costs, reducing formation damage and promoting environmental protection. They are an indispensable tool in oil and gas field development.

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